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Double uranium oxo cations derived from uranyl by borane or silane reduction

A new type of double uranium oxo cation [O–U–O–U–O](4+) is prepared by selective oxygen-atom abstraction from macrocyclic uranyl complexes using either boranes or silanes. A significant degree of multiple U[double bond, length as m-dash]O bonding is evident throughout the U(2)O(3) core, but either t...

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Detalles Bibliográficos
Autores principales:	Cowie, Bradley E., Nichol, Gary S., Love, Jason B., Arnold, Polly L.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5932998/ https://www.ncbi.nlm.nih.gov/pubmed/29589007 http://dx.doi.org/10.1039/c8cc00341f

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