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The role of charge in 1,2,3-triazol(ium)-based halogen bonding activators

The influence of charge on the performance of monocationic and dicationic triazol(ium)-based halogen bond donors was investigated. Next to the activity in a halide abstraction benchmark reaction, halogen bonding was also evaluated via X-ray structural analyses and isothermal titration calorimetry.

Detalles Bibliográficos
Autores principales: Dreger, Alexander, Engelage, Elric, Mallick, Bert, Beer, Paul D., Huber, Stefan M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5933004/
https://www.ncbi.nlm.nih.gov/pubmed/29617018
http://dx.doi.org/10.1039/c8cc00527c