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Step-growth titanium-catalysed dehydropolymerisation of amine–boranes

Precatalysts active for the dehydropolymerisation of primary amine–boranes are generally based on mid or late transition metal. We have found that the activity of the precatalyst system formed from Cp(R)(2)TiCl(2) and 2nBuLi towards the dehydrogenation of the secondary amine–borane Me(2)NH·BH(3), to...

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Detalles Bibliográficos
Autores principales: Jurca, Titel, Dellermann, Theresa, Stubbs, Naomi E., Resendiz-Lara, Diego A., Whittell, George R., Manners, Ian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5933219/
https://www.ncbi.nlm.nih.gov/pubmed/29780466
http://dx.doi.org/10.1039/c7sc05395a