Room temperature olefination of methane with titanium–carbon multiple bonds

C–H activation of methane followed by dehydrocoupling at room temperature led ultimately to the formation of the olefin H(2)C[double bond, length as m-dash]CH(t)Bu via the addition of redox-active ligands (L) such as thioxanthone or 2,2′-bipyridine (bipy) to (PNP)Ti[double bond, length as m-dash]CH(...

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Detalles Bibliográficos
Autores principales: Kurogi, Takashi, Won, Joonghee, Park, Bohyun, Trofymchuk, Oleksandra S., Carroll, Patrick J., Baik, Mu-Hyun, Mindiola, Daniel J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5933228/
https://www.ncbi.nlm.nih.gov/pubmed/29780468
http://dx.doi.org/10.1039/c7sc05238c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5933228/
https://www.ncbi.nlm.nih.gov/pubmed/29780468
http://dx.doi.org/10.1039/c7sc05238c

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