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Room temperature olefination of methane with titanium–carbon multiple bonds
C–H activation of methane followed by dehydrocoupling at room temperature led ultimately to the formation of the olefin H(2)C[double bond, length as m-dash]CH(t)Bu via the addition of redox-active ligands (L) such as thioxanthone or 2,2′-bipyridine (bipy) to (PNP)Ti[double bond, length as m-dash]CH(...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5933228/ https://www.ncbi.nlm.nih.gov/pubmed/29780468 http://dx.doi.org/10.1039/c7sc05238c |