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Donor–acceptor interactions between cyclic trinuclear pyridinate gold(i)-complexes and electron-poor guests: nature and energetics of guest-binding and templating on graphite

Donor–acceptor-type interactions between π-electron systems are of high relevance in the design of chemical sensors. Due to their electron-rich nature, cyclic trinuclear complexes (CTCs) of gold(i) are ideal receptor sites for electron-deficient aromatic analytes. Scanning tunneling microscopy provi...

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Detalles Bibliográficos
Autores principales: Hahn, Raiko, Bohle, Fabian, Kotte, Stefan, Keller, Tristan J., Jester, Stefan-S., Hansen, Andreas, Grimme, Stefan, Esser, Birgit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5934696/
https://www.ncbi.nlm.nih.gov/pubmed/29780477
http://dx.doi.org/10.1039/c7sc05355j