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Unexpected solvation-stabilisation of ions in a protic ionic liquid: insights disclosed by a bond energetic study
Equilibrium acidities (pK(a)s) of 42 organic acids were precisely determined in protic ionic liquid (PIL) [DBUH][OTf]. Surprisingly, the often seen homoassociation complication during the pK(a) measurement of O–H acids in DMSO was not detected in [DBUH][OTf], implying that the incipient oxanion shou...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5934747/ https://www.ncbi.nlm.nih.gov/pubmed/29780485 http://dx.doi.org/10.1039/c7sc05227h |