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Unexpected solvation-stabilisation of ions in a protic ionic liquid: insights disclosed by a bond energetic study

Equilibrium acidities (pK(a)s) of 42 organic acids were precisely determined in protic ionic liquid (PIL) [DBUH][OTf]. Surprisingly, the often seen homoassociation complication during the pK(a) measurement of O–H acids in DMSO was not detected in [DBUH][OTf], implying that the incipient oxanion shou...

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Detalles Bibliográficos
Autores principales:	Wang, Zhen, Gao, Feixiang, Ji, Pengju, Cheng, Jin-Pei
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5934747/ https://www.ncbi.nlm.nih.gov/pubmed/29780485 http://dx.doi.org/10.1039/c7sc05227h

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