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Using stereoretention for the synthesis of E-macrocycles with ruthenium-based olefin metathesis catalysts
The synthesis of E-macrocycles is achieved using stereoretentive, Ru-based olefin metathesis catalysts supported by dithiolate ligands. Kinetic studies elucidate marked differences in activity among the catalysts tested, with catalyst 4 providing meaningful yields of products in much shorter reactio...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5934820/ https://www.ncbi.nlm.nih.gov/pubmed/29780490 http://dx.doi.org/10.1039/c8sc00435h |