Chemoselective Hydrogenation of Aldehydes under Mild, Base-Free Conditions: Manganese Outperforms Rhenium

[Image: see text] Several hydride Mn(I) and Re(I) PNP pincer complexes were applied as catalysts for the homogeneous chemoselective hydrogenation of aldehydes. Among these, [Mn(PNP-iPr)(CO)(2)(H)] was found to be one of the most efficient base metal catalysts for this process and represents a rare e...

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Detalles Bibliográficos
Autores principales: Glatz, Mathias, Stöger, Berthold, Himmelbauer, Daniel, Veiros, Luis F., Kirchner, Karl
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5939901/
https://www.ncbi.nlm.nih.gov/pubmed/29755828
http://dx.doi.org/10.1021/acscatal.8b00153

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5939901/
https://www.ncbi.nlm.nih.gov/pubmed/29755828
http://dx.doi.org/10.1021/acscatal.8b00153

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