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The role of cations in the interactions between anionic N-heterocycles and SO(2)

Our study shows that cation plays a more important role in the interactions between anionic N-heterocycles and SO(2) than in the NHC-CO(2) case. The adducts of NHC, SO(2) and cation often exhibit multiple stable configurations with close energies rather than the only reported “CO(2)-sandwiched” plan...

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Detalles Bibliográficos
Autores principales: Li, Chenchen, Lu, Dongmei, Wu, Chao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5940702/
https://www.ncbi.nlm.nih.gov/pubmed/29740023
http://dx.doi.org/10.1038/s41598-018-25432-6