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The role of cations in the interactions between anionic N-heterocycles and SO(2)
Our study shows that cation plays a more important role in the interactions between anionic N-heterocycles and SO(2) than in the NHC-CO(2) case. The adducts of NHC, SO(2) and cation often exhibit multiple stable configurations with close energies rather than the only reported “CO(2)-sandwiched” plan...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5940702/ https://www.ncbi.nlm.nih.gov/pubmed/29740023 http://dx.doi.org/10.1038/s41598-018-25432-6 |