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Pd(ii)-catalyzed synthesis of bifunctionalized carboranes via cage B–H activation of 1-CH(2)NH(2)-o-carboranes

Aminoalkyl carboranes are anticipated to be valuable synthons toward the synthesis of bifunctionalized carboranes. However, direct cage boron derivation of these carborane derivatives has not been solved. Herein, the reversible conversion of catalytically infeasible o-carboranyl methylamines (1-CH(2...

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Detalles Bibliográficos
Autores principales: Zhang, Xiaolei, Yan, Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5941203/
https://www.ncbi.nlm.nih.gov/pubmed/29780529
http://dx.doi.org/10.1039/c8sc01154k