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Pd(ii)-catalyzed synthesis of bifunctionalized carboranes via cage B–H activation of 1-CH(2)NH(2)-o-carboranes
Aminoalkyl carboranes are anticipated to be valuable synthons toward the synthesis of bifunctionalized carboranes. However, direct cage boron derivation of these carborane derivatives has not been solved. Herein, the reversible conversion of catalytically infeasible o-carboranyl methylamines (1-CH(2...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5941203/ https://www.ncbi.nlm.nih.gov/pubmed/29780529 http://dx.doi.org/10.1039/c8sc01154k |