Unusual mechanisms in Claisen rearrangements: an ionic fragmentation leading to a meta-selective rearrangement

A mechanistic investigation of the acid-catalysed redox-neutral oxoarylation reaction of ynamides using electrospray ionisation mass-spectrometry (ESI-MS) and quantum chemical calculations (DFT and MP2) is presented. This study reveals the diversity of pathways and products available from an otherwi...

Descripción completa

Detalles Bibliográficos
Autores principales: Maryasin, Boris, Kaldre, Dainis, Galaverna, Renan, Klose, Immo, Ruider, Stefan, Drescher, Martina, Kählig, Hanspeter, González, Leticia, Eberlin, Marcos N., Jurberg, Igor D., Maulide, Nuno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5941282/
https://www.ncbi.nlm.nih.gov/pubmed/29780542
http://dx.doi.org/10.1039/c7sc04736c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5941282/
https://www.ncbi.nlm.nih.gov/pubmed/29780542
http://dx.doi.org/10.1039/c7sc04736c

Ejemplares similares