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Unusual mechanisms in Claisen rearrangements: an ionic fragmentation leading to a meta-selective rearrangement

A mechanistic investigation of the acid-catalysed redox-neutral oxoarylation reaction of ynamides using electrospray ionisation mass-spectrometry (ESI-MS) and quantum chemical calculations (DFT and MP2) is presented. This study reveals the diversity of pathways and products available from an otherwi...

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Detalles Bibliográficos
Autores principales:	Maryasin, Boris, Kaldre, Dainis, Galaverna, Renan, Klose, Immo, Ruider, Stefan, Drescher, Martina, Kählig, Hanspeter, González, Leticia, Eberlin, Marcos N., Jurberg, Igor D., Maulide, Nuno
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5941282/ https://www.ncbi.nlm.nih.gov/pubmed/29780542 http://dx.doi.org/10.1039/c7sc04736c

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