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Nontrigonal constraint enhances 1,2-addition reactivity of phosphazenes

The syntheses and 1,2-addition reactivities of nontrigonal phosphazenes supported by trianionic tricoordinating chelates of the type L(3)P[double bond, length as m-dash]Ndipp (3: L(3) = N[CHC((t)Bu)O](2)(3–); 4: L(3) = N(o-NMeC(6)H(4))(2)(3–); dipp = 2,6-diisopropylphenyl) are reported. These compou...

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Detalles Bibliográficos
Autores principales: Lin, Yi-Chun, Gilhula, James C., Radosevich, Alexander T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5944378/
https://www.ncbi.nlm.nih.gov/pubmed/29780566
http://dx.doi.org/10.1039/c8sc00929e