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Chemical structure and bonding in a thorium(iii)–aluminum heterobimetallic complex

Thorium sits at a unique position on the periodic table. On one hand, there is little evidence that its 5f orbitals engage in bonding as they do in other early actinides; on the other hand, its chemistry is distinct from Lewis acidic transition metals. To gain insight into the underlying electronic...

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Detalles Bibliográficos
Autores principales: Altman, Alison B., Brown, Alexandra C., Rao, Guodong, Lohrey, Trevor D., Britt, R. David, Maron, Laurent, Minasian, Stefan G., Shuh, David K., Arnold, John
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5944380/
https://www.ncbi.nlm.nih.gov/pubmed/29780563
http://dx.doi.org/10.1039/c8sc01260a