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Chemical structure and bonding in a thorium(iii)–aluminum heterobimetallic complex
Thorium sits at a unique position on the periodic table. On one hand, there is little evidence that its 5f orbitals engage in bonding as they do in other early actinides; on the other hand, its chemistry is distinct from Lewis acidic transition metals. To gain insight into the underlying electronic...
Autores principales: | Altman, Alison B., Brown, Alexandra C., Rao, Guodong, Lohrey, Trevor D., Britt, R. David, Maron, Laurent, Minasian, Stefan G., Shuh, David K., Arnold, John |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5944380/ https://www.ncbi.nlm.nih.gov/pubmed/29780563 http://dx.doi.org/10.1039/c8sc01260a |
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