Cargando…

Taming a monomeric [Cu(η(6)-C(6)H(6))](+) complex with silylene

Previous theoretical and experimental endeavors suggested that [Cu(C(6)H(6))](+) prefers the η(1)/η(2) mode over the η(6) mode due to the augmented repulsion between the benzene ring and metal d-electrons. Nevertheless, the use of silylene as a neutral ligand has led to the isolation of the first mo...

Descripción completa

Detalles Bibliográficos
Autores principales: Parvin, Nasrina, Pal, Shiv, Echeverría, Jorge, Alvarez, Santiago, Khan, Shabana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5944381/
https://www.ncbi.nlm.nih.gov/pubmed/29780565
http://dx.doi.org/10.1039/c8sc00459e