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Taming a monomeric [Cu(η(6)-C(6)H(6))](+) complex with silylene
Previous theoretical and experimental endeavors suggested that [Cu(C(6)H(6))](+) prefers the η(1)/η(2) mode over the η(6) mode due to the augmented repulsion between the benzene ring and metal d-electrons. Nevertheless, the use of silylene as a neutral ligand has led to the isolation of the first mo...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5944381/ https://www.ncbi.nlm.nih.gov/pubmed/29780565 http://dx.doi.org/10.1039/c8sc00459e |