Spirocyclic germanes via transannular insertion reactions of vinyl germylenes into Si–Si bonds

The reactions of two cyclic germylene phosphane adducts with monosubstituted acetylenes caused the formation of spirocyclic germanes, which is postulated to occur by double acetylene insertion into germylene attached bonds. Further insertion of the formed cyclic divinylgermylene into transannular Si...

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Detalles Bibliográficos
Autores principales: Walewska, Małgorzata, Baumgartner, Judith, Marschner, Christoph, Albers, Lena, Müller, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5946683/
https://www.ncbi.nlm.nih.gov/pubmed/29658036
http://dx.doi.org/10.1039/c8dt00315g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5946683/
https://www.ncbi.nlm.nih.gov/pubmed/29658036
http://dx.doi.org/10.1039/c8dt00315g

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