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Spirocyclic germanes via transannular insertion reactions of vinyl germylenes into Si–Si bonds
The reactions of two cyclic germylene phosphane adducts with monosubstituted acetylenes caused the formation of spirocyclic germanes, which is postulated to occur by double acetylene insertion into germylene attached bonds. Further insertion of the formed cyclic divinylgermylene into transannular Si...
Autores principales: | Walewska, Małgorzata, Baumgartner, Judith, Marschner, Christoph, Albers, Lena, Müller, Thomas |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5946683/ https://www.ncbi.nlm.nih.gov/pubmed/29658036 http://dx.doi.org/10.1039/c8dt00315g |
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