A Highly Active N‐Heterocyclic Carbene Manganese(I) Complex for Selective Electrocatalytic CO(2) Reduction to CO

We report here the first purely organometallic fac‐[Mn(I)(CO)(3)(bis‐(Me)NHC)Br] complex with unprecedented activity for the selective electrocatalytic reduction of CO(2) to CO, exceeding 100 turnovers with excellent faradaic yields (η (CO)≈95 %) in anhydrous CH(3)CN. Under the same conditions, a ma...

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Detalles Bibliográficos
Autores principales: Franco, Federico, Pinto, Mara F., Royo, Beatriz, Lloret‐Fillol, Julio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947128/
https://www.ncbi.nlm.nih.gov/pubmed/29481726
http://dx.doi.org/10.1002/anie.201800705

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947128/
https://www.ncbi.nlm.nih.gov/pubmed/29481726
http://dx.doi.org/10.1002/anie.201800705

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