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Highly selective hydrogenation of CO(2) into C(2+) alcohols by homogeneous catalysis

The hydrogenation of CO(2) to produce alcohols with two or more carbons (C(2+) alcohols) is of great importance, but is challenging. In this work, we found that a Ru(3)(CO)(12)/Rh(2)(CO)(4)Cl(2)–LiI system could catalyze the reaction effectively in 1,3-dimethyl-2-imidazolidinone (DMI) under mild con...

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Detalles Bibliográficos
Autores principales: Qian, Qingli, Cui, Meng, He, Zhenhong, Wu, Congyi, Zhu, Qinggong, Zhang, Zhaofu, Ma, Jun, Yang, Guanying, Zhang, Jingjing, Han, Buxing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947507/
https://www.ncbi.nlm.nih.gov/pubmed/29861902
http://dx.doi.org/10.1039/c5sc02000j