Magnesium-catalyzed hydrosilylation of α,β-unsaturated esters

To(M)MgHB(C(6)F(5))(3) (1, To(M) = tris(4,4-dimethyl-2-oxazolinyl)phenylborate) catalyzes the 1,4-hydrosilylation of α,β-unsaturated esters. This magnesium hydridoborate compound is synthesized by the reaction of To(M)MgMe, PhSiH(3), and B(C(6)F(5))(3). Unlike the transient To(M)MgH formed from the...

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Detalles Bibliográficos
Autores principales: Lampland, Nicole L., Pindwal, Aradhana, Neal, Steven R., Schlauderaff, Shealyn, Ellern, Arkady, Sadow, Aaron D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947512/
https://www.ncbi.nlm.nih.gov/pubmed/29861929
http://dx.doi.org/10.1039/c5sc02435h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947512/
https://www.ncbi.nlm.nih.gov/pubmed/29861929
http://dx.doi.org/10.1039/c5sc02435h

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