Comparison of rhenium–porphyrin dyads for CO(2) photoreduction: photocatalytic studies and charge separation dynamics studied by time-resolved IR spectroscopy

We report a study of the photocatalytic reduction of CO(2) to CO by zinc porphyrins covalently linked to [Re(I)(2,2′-bipyridine)(CO)(3)L](+/0) moieties with visible light of wavelength >520 nm. Dyad 1 contains an amide C(6)H(4)NHC(O) link from porphyrin to bipyridine (Bpy), Dyad 2 contains an add...

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Detalles Bibliográficos
Autores principales: Windle, Christopher D., George, Michael W., Perutz, Robin N., Summers, Peter A., Sun, Xue Zhong, Whitwood, Adrian C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947513/
https://www.ncbi.nlm.nih.gov/pubmed/29861927
http://dx.doi.org/10.1039/c5sc02099a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947513/
https://www.ncbi.nlm.nih.gov/pubmed/29861927
http://dx.doi.org/10.1039/c5sc02099a

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