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Comparison of rhenium–porphyrin dyads for CO(2) photoreduction: photocatalytic studies and charge separation dynamics studied by time-resolved IR spectroscopy
We report a study of the photocatalytic reduction of CO(2) to CO by zinc porphyrins covalently linked to [Re(I)(2,2′-bipyridine)(CO)(3)L](+/0) moieties with visible light of wavelength >520 nm. Dyad 1 contains an amide C(6)H(4)NHC(O) link from porphyrin to bipyridine (Bpy), Dyad 2 contains an add...
Autores principales: | Windle, Christopher D., George, Michael W., Perutz, Robin N., Summers, Peter A., Sun, Xue Zhong, Whitwood, Adrian C. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947513/ https://www.ncbi.nlm.nih.gov/pubmed/29861927 http://dx.doi.org/10.1039/c5sc02099a |
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