Non-decarbonylative photochemical versus thermal activation of Bu(4)N[Fe(CO)(3)(NO)] – the Fe-catalyzed Cloke–Wilson rearrangement of vinyl and arylcyclopropanes

The base metal complex Bu(4)N[Fe(CO)(3)(NO)] (TBA[Fe]) catalyzes the rearrangement of vinyl and arylcyclopropanes both under thermal or photochemical conditions to give the corresponding vinyl or aryldihydrofurans in good to excellent yields. Under photochemical conditions the reaction is performed...

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Detalles Bibliográficos
Autores principales: Lin, Che-Hung, Pursley, Dominik, Klein, Johannes E. M. N., Teske, Johannes, Allen, Jennifer A., Rami, Fabian, Köhn, Andreas, Plietker, Bernd
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947516/
https://www.ncbi.nlm.nih.gov/pubmed/29861942
http://dx.doi.org/10.1039/c5sc02342d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947516/
https://www.ncbi.nlm.nih.gov/pubmed/29861942
http://dx.doi.org/10.1039/c5sc02342d

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