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Non-decarbonylative photochemical versus thermal activation of Bu(4)N[Fe(CO)(3)(NO)] – the Fe-catalyzed Cloke–Wilson rearrangement of vinyl and arylcyclopropanes
The base metal complex Bu(4)N[Fe(CO)(3)(NO)] (TBA[Fe]) catalyzes the rearrangement of vinyl and arylcyclopropanes both under thermal or photochemical conditions to give the corresponding vinyl or aryldihydrofurans in good to excellent yields. Under photochemical conditions the reaction is performed...
Autores principales: | Lin, Che-Hung, Pursley, Dominik, Klein, Johannes E. M. N., Teske, Johannes, Allen, Jennifer A., Rami, Fabian, Köhn, Andreas, Plietker, Bernd |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947516/ https://www.ncbi.nlm.nih.gov/pubmed/29861942 http://dx.doi.org/10.1039/c5sc02342d |
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