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2(nd) coordination sphere controlled electron transfer of iron hangman complexes on electrodes probed by surface enhanced vibrational spectroscopy

Iron hangman complexes exhibit improved catalytic properties regarding O(2) and H(2)O(2) reduction, which are attributed to the presence of a proton donating group in defined vicinity of the catalytic metal centre. Surface enhanced resonance Raman (SERR) and IR (SEIRA) spectro-electrochemistry has b...

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Detalles Bibliográficos
Autores principales: Ly, H. K., Wrzolek, P., Heidary, N., Götz, R., Horch, M., Kozuch, J., Schwalbe, M., Weidinger, I. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947519/
https://www.ncbi.nlm.nih.gov/pubmed/29861938
http://dx.doi.org/10.1039/c5sc02560e