Spacer Length‐Independent Shuttling of the Pillar[5]arene Ring in Neutral [2]Rotaxanes

For a series of neutral [2]rotaxanes consisting of a pillar[5]arene ring and axles possessing two stations separated by flexible spacers of different lengths, the free energies of activation for the ring shuttling between the stations were found to be independent of the spacer length. The constituti...

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Detalles Bibliográficos
Autores principales: Ogoshi, Tomoki, Kotera, Daisuke, Nishida, Shungo, Kakuta, Takahiro, Yamagishi, Tada‐aki, Brouwer, Albert M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947626/
https://www.ncbi.nlm.nih.gov/pubmed/29473232
http://dx.doi.org/10.1002/chem.201800104

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947626/
https://www.ncbi.nlm.nih.gov/pubmed/29473232
http://dx.doi.org/10.1002/chem.201800104

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