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Spacer Length‐Independent Shuttling of the Pillar[5]arene Ring in Neutral [2]Rotaxanes
For a series of neutral [2]rotaxanes consisting of a pillar[5]arene ring and axles possessing two stations separated by flexible spacers of different lengths, the free energies of activation for the ring shuttling between the stations were found to be independent of the spacer length. The constituti...
Autores principales: | Ogoshi, Tomoki, Kotera, Daisuke, Nishida, Shungo, Kakuta, Takahiro, Yamagishi, Tada‐aki, Brouwer, Albert M. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947626/ https://www.ncbi.nlm.nih.gov/pubmed/29473232 http://dx.doi.org/10.1002/chem.201800104 |
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