Synthesis and crystal structure of deca­carbon­yl(μ(3)-3,7-di­thia­nonane-1,9-di­thiol­ato)bis­(μ(2)-propane-1,3-di­thiol­ato)nickel(II)tetra­iron(II) di­chloro­methane disolvate

The title compound,, [Fe(4)Ni(C(3)H(6)S(2))(2)(C(7)H(14)S(4))(CO)(10)]·2CH(2)Cl(2), is reported as a biomimic model for the active site of [FeFe]-hydrogenases. Bis(2-mercaptoeth­yl)-1,3-propane­dithio ether nickel(II) was firstly introduced into [Fe(2)(C(3)H(6)S(2))(CO)(5)] as an S-containing ligand...

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Detalles Bibliográficos
Autores principales: Ren, Gan, Sang, Ge
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947796/
https://www.ncbi.nlm.nih.gov/pubmed/29765716
http://dx.doi.org/10.1107/S2056989018001731

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947796/
https://www.ncbi.nlm.nih.gov/pubmed/29765716
http://dx.doi.org/10.1107/S2056989018001731

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