Experimental demonstration of pH-dependent electrostatic catalysis of radical reactions

Time-dependent fluorescence spectroscopy has been used to demonstrate significant pH-dependent electrostatic effects on the kinetics and thermodynamics of hydrogen atom transfer between 1-hydroxy-2,2,6,6-tetramethyl-4-piperidinecarboxylic acid (4-CT-H) and the profluorescent nitroxide {2,2,6,6-tetra...

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Detalles Bibliográficos
Autores principales: Klinska, Marta, Smith, Leesa M., Gryn'ova, Ganna, Banwell, Martin G., Coote, Michelle L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5949849/
https://www.ncbi.nlm.nih.gov/pubmed/29861899
http://dx.doi.org/10.1039/c5sc01307k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5949849/
https://www.ncbi.nlm.nih.gov/pubmed/29861899
http://dx.doi.org/10.1039/c5sc01307k

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