Enantioselective gold-catalyzed intermolecular [2+2] versus [4+2]-cycloadditions of 3-styrylindoles with N-allenamides: observation of interesting substituent effects

A highly enantioselective [2+2] versus a [4+2]-cycloaddition of 3-styrylindoles to N-allenamides catalyzed by identical gold(i)/chiral phosphoramidite complexes is presented, which provides facile access to synthetically valuable, optically active substituted cyclobutanes and tetrahydrocarbazoles. T...

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Detalles Bibliográficos
Autores principales: Wang, Yidong, Zhang, Peichao, Liu, Yuan, Xia, Fei, Zhang, Junliang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5949851/
https://www.ncbi.nlm.nih.gov/pubmed/29861893
http://dx.doi.org/10.1039/c5sc01827g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5949851/
https://www.ncbi.nlm.nih.gov/pubmed/29861893
http://dx.doi.org/10.1039/c5sc01827g

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