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Rh(I)/Rh(III) catalyst-controlled divergent aryl/heteroaryl C–H bond functionalization of picolinamides with alkynes

The ability to establish switchable site-selectivity through catalyst control in the direct functionalization of molecules that contain distinct C–H bonds remains a demanding challenge that would enable the construction of diverse scaffolds from the same starting materials. Herein we describe the re...

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Detalles Bibliográficos
Autores principales: Martínez, Ángel Manu, Echavarren, Javier, Alonso, Inés, Rodríguez, Nuria, Gómez Arrayás, Ramón, Carretero, Juan C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5950197/
https://www.ncbi.nlm.nih.gov/pubmed/29861907
http://dx.doi.org/10.1039/c5sc01885d