Trimetallaborides as starting points for the syntheses of large metal-rich molecular borides and clusters

Treatment of an anionic dimanganaborylene complex ([{Cp(CO)(2)Mn}(2)B](–)) with coinage metal cations stabilized by a very weakly coordinating Lewis base (SMe(2)) led to the coordination of the incoming metal and subsequent displacement of dimethylsulfide in the formation of hexametalladiborides fea...

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Detalles Bibliográficos
Autores principales: Braunschweig, Holger, Ewing, William C., Ghosh, Sundargopal, Kramer, Thomas, Mattock, James D., Östreicher, Sebastian, Vargas, Alfredo, Werner, Christine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5950574/
https://www.ncbi.nlm.nih.gov/pubmed/29861971
http://dx.doi.org/10.1039/c5sc03206g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5950574/
https://www.ncbi.nlm.nih.gov/pubmed/29861971
http://dx.doi.org/10.1039/c5sc03206g

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