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Trimetallaborides as starting points for the syntheses of large metal-rich molecular borides and clusters
Treatment of an anionic dimanganaborylene complex ([{Cp(CO)(2)Mn}(2)B](–)) with coinage metal cations stabilized by a very weakly coordinating Lewis base (SMe(2)) led to the coordination of the incoming metal and subsequent displacement of dimethylsulfide in the formation of hexametalladiborides fea...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5950574/ https://www.ncbi.nlm.nih.gov/pubmed/29861971 http://dx.doi.org/10.1039/c5sc03206g |