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Two-coordinate group 14 element(ii) hydrides as reagents for the facile, and sometimes reversible, hydrogermylation/hydrostannylation of unactivated alkenes and alkynes
Reactions of the solution stable, two-coordinate hydrido-tetrylenes, :E(H)(L(†)) (E = Ge or Sn; L(†) = –N(Ar(†))(SiPr(i)(3)); Ar(†) = C(6)H(2){C(H)Ph(2)}(2)Pr(i)-2,6,4), with a variety of unactivated cyclic and acyclic alkenes, and one internal alkyne, lead to the rapid and regiospecific hydrometall...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5950753/ https://www.ncbi.nlm.nih.gov/pubmed/29861960 http://dx.doi.org/10.1039/c5sc03376d |