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Synthesis, structure and reactivity of a terminal magnesium fluoride compound, [Tp(Bu(t),Me)]MgF: hydrogen bonding, halogen bonding and C–F bond formation
The bulky tris(3-tert-butyl-5-pyrazolyl)hydroborato ligand, [Tp(Bu(t),Me)], has been employed to obtain the first structurally characterized example of a molecular magnesium compound that features a terminal fluoride ligand, namely [Tp(Bu(t),Me)]MgF, via the reaction of [Tp(Bu(t),Me)]MgMe with Me(3)...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5950829/ https://www.ncbi.nlm.nih.gov/pubmed/29861975 http://dx.doi.org/10.1039/c5sc03504j |