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Control of cerium oxidation state through metal complex secondary structures
A series of alkali metal cerium diphenylhydrazido complexes, M(x)(py)(y)[Ce(PhNNPh)(4)], M = Li, Na, and K, x = 4 (Li and Na) or 5 (K), and y = 4 (Li), 8 (Na), or 7 (K), were synthesized to probe how a secondary coordination sphere would modulate electronic structures at a cerium cation. The resulti...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5951102/ https://www.ncbi.nlm.nih.gov/pubmed/29861931 http://dx.doi.org/10.1039/c5sc02607e |