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Platinum(ii) complexes of mixed-valent radicals derived from cyclotricatechylene, a macrocyclic tris-dioxolene

Three complexes of cyclotricatechylene (H(6)ctc), [{PtL}(3)(μ(3)-ctc)], have been synthesised: (L = 1,2-bis(diphenylphosphino)benzene {dppb}, 1; L = 1,2-bis(diphenylphosphino)ethane {dppe}, 2; L = 4,4′-bis(tert-butyl)-2,2′-bipyridyl {(t)Bu(2)bipy}, 3). The complexes show three low-potential, chemica...

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Detalles Bibliográficos
Autores principales: Loughrey, Jonathan J., Patmore, Nathan J., Baldansuren, Amgalanbaatar, Fielding, Alistair J., McInnes, Eric J. L., Hardie, Michaele J., Sproules, Stephen, Halcrow, Malcolm A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5951140/
https://www.ncbi.nlm.nih.gov/pubmed/29861932
http://dx.doi.org/10.1039/c5sc02776d