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Platinum(ii) complexes of mixed-valent radicals derived from cyclotricatechylene, a macrocyclic tris-dioxolene
Three complexes of cyclotricatechylene (H(6)ctc), [{PtL}(3)(μ(3)-ctc)], have been synthesised: (L = 1,2-bis(diphenylphosphino)benzene {dppb}, 1; L = 1,2-bis(diphenylphosphino)ethane {dppe}, 2; L = 4,4′-bis(tert-butyl)-2,2′-bipyridyl {(t)Bu(2)bipy}, 3). The complexes show three low-potential, chemica...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5951140/ https://www.ncbi.nlm.nih.gov/pubmed/29861932 http://dx.doi.org/10.1039/c5sc02776d |