The first chiral diene-based metal–organic frameworks for highly enantioselective carbon–carbon bond formation reactions

We have designed the first chiral diene-based metal–organic framework (MOF), E(2)-MOF, and postsynthetically metalated E(2)-MOF with Rh(i) complexes to afford highly active and enantioselective single-site solid catalysts for C–C bond formation reactions. Treatment of E(2)-MOF with [RhCl(C(2)H(4))(2...

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Detalles Bibliográficos
Autores principales: Sawano, Takahiro, Ji, Pengfei, McIsaac, Alexandra R., Lin, Zekai, Abney, Carter W., Lin, Wenbin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5951194/
https://www.ncbi.nlm.nih.gov/pubmed/29861953
http://dx.doi.org/10.1039/c5sc02100f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5951194/
https://www.ncbi.nlm.nih.gov/pubmed/29861953
http://dx.doi.org/10.1039/c5sc02100f

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