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The first chiral diene-based metal–organic frameworks for highly enantioselective carbon–carbon bond formation reactions
We have designed the first chiral diene-based metal–organic framework (MOF), E(2)-MOF, and postsynthetically metalated E(2)-MOF with Rh(i) complexes to afford highly active and enantioselective single-site solid catalysts for C–C bond formation reactions. Treatment of E(2)-MOF with [RhCl(C(2)H(4))(2...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5951194/ https://www.ncbi.nlm.nih.gov/pubmed/29861953 http://dx.doi.org/10.1039/c5sc02100f |