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Peripheral mechanism of a carbonyl hydrosilylation catalysed by an SiNSi iron pincer complex
Combined experimental and theoretical analysis of the carbonyl hydrosilylation catalysed by an iron(0) pincer complex reveals an unprecedented mechanism of action. The iron(0) complex is in fact a precatalyst that is converted into an iron(ii) catalyst through oxidative addition of a hydrosilane. Ne...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5951209/ https://www.ncbi.nlm.nih.gov/pubmed/29861950 http://dx.doi.org/10.1039/c5sc02855h |