Mechanism of the Cu(II)-catalyzed benzylic oxygenation of (aryl)(heteroaryl)methanes with oxygen

A mechanistic study of the copper-catalyzed oxidation of the methylene group of aryl(di)azinylmethanes was performed. Initial reaction rates were measured making use of in situ IR reaction monitoring and a kinetic analysis of the reaction was executed. The reaction proved to be first order in oxygen...

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Detalles Bibliográficos
Autores principales: Sterckx, Hans, De Houwer, Johan, Mensch, Carl, Caretti, Ignacio, Tehrani, Kourosch Abbaspour, Herrebout, Wouter A., Van Doorslaer, Sabine, Maes, Bert U. W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5952523/
https://www.ncbi.nlm.nih.gov/pubmed/29861987
http://dx.doi.org/10.1039/c5sc03530a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5952523/
https://www.ncbi.nlm.nih.gov/pubmed/29861987
http://dx.doi.org/10.1039/c5sc03530a

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