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Mechanism of the Cu(II)-catalyzed benzylic oxygenation of (aryl)(heteroaryl)methanes with oxygen
A mechanistic study of the copper-catalyzed oxidation of the methylene group of aryl(di)azinylmethanes was performed. Initial reaction rates were measured making use of in situ IR reaction monitoring and a kinetic analysis of the reaction was executed. The reaction proved to be first order in oxygen...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5952523/ https://www.ncbi.nlm.nih.gov/pubmed/29861987 http://dx.doi.org/10.1039/c5sc03530a |