Enantiodivergent asymmetric catalysis with the tropos BIPHEP ligand and a proline derivative as chiral selector

A catalytic system based on the tropos ligand BIPHEP and (S)-proline methyl ester as chiral selector was studied for Rh-catalysed asymmetric catalysis. By careful control of the catalyst preformation conditions, the enantioselectivity could be completely reversed in asymmetric hydrogenation of proch...

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Detalles Bibliográficos
Autores principales: Oczipka, P., Müller, D., Leitner, W., Franciò, G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5952544/
https://www.ncbi.nlm.nih.gov/pubmed/29861999
http://dx.doi.org/10.1039/c5sc03465e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5952544/
https://www.ncbi.nlm.nih.gov/pubmed/29861999
http://dx.doi.org/10.1039/c5sc03465e

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