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Reversible [4 + 2] cycloaddition reaction of 1,3,2,5-diazadiborinine with ethylene

Under ambient conditions, a [4 + 2] cycloaddition reaction of 1,3,2,5-diazadiborinine 1 with ethylene afforded a bicyclo[2.2.2] derivative 2, which was structurally characterized. The cyclization process was found to be reversible, and thus retro-[4 + 2] cycloaddition reproduced 1 quantitatively, co...

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Detalles Bibliográficos
Autores principales: Wu, Di, Ganguly, Rakesh, Li, Yongxin, Hoo, Sin Ni, Hirao, Hajime, Kinjo, Rei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5952552/
https://www.ncbi.nlm.nih.gov/pubmed/29861951
http://dx.doi.org/10.1039/c5sc03174e